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The complex-formation equilibria of mercury(II) with acetylcysteine and captopril have been studied by pH-metric and liquid-liquid extraction methods applying dithizone as a competitive ligand during the latter measurements. The stability constants of three differently protonated Hg(II)/ligand 1:2 complexes of extreme stability have been determined by the combination of extraction and pH-metric data.

Comparative Studies on the Complex-Formation Equilibria of Mercury(II) with Acetylcysteine and Captopril