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The synthesis, molecular and crystal structure of ( n BuSn) 9 (V V O) 3 O 14 (OH) 6 Cl 2 (dmso) 2  · 3 DMSO ( 1 ) are described. The yellow compound crystallizes in the monoclinic space group  P 2(1)/ n  (No. 14) with  a  = 17.961(5) Å,  b  = 19.222(4) Å,  c  = 26.748(6) Å,  β  = 106.776(2)°,  V  = 8842(4) Å 3 ,  Z  = 4. The neutral monoorganotin-polyoxo-vanadium molecule ( n BuSn) 9 (V V O) 3 O 14 (OH) 6 Cl 2  × (dmso) 2  ( 1a ) shows the same distorted icosahedral arrangement of the metal atoms and a very similar metal-oxygen framework as the well known [( i PrSn) 12 O 14 (OH) 6 ] 2+  ion ( 2 ) from which it can be derived formally by substitution of three square pyramidally coordinated {RSnO 4 } groups by three {OVO 4 } groups of the same geometry. In addition, two further {RSnO 4 } groups are replaced by two octahedral {RSnO 3 Cl(dmso)} units.

Monoorganotin-polyoxometal-compounds – III. Synthesis and crystal structure of [( n BuSn) 9 (V V O) 3 O 14 (OH) 6 Cl 2 (dmso) 2 ] · 3DMSO