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The crystal field parameter 10Dq [cm⁻¹]  of octahedral chromium obtained as the energy of the  4 A 2g  →  4 T 2g  band of Cr 3+  in the electronic absorption spectra, EAS, of a series of 13 natural grossular-uvarovite garnets with compositions close to the binary join Ca 3 (Al 1–   x  Cr  x  ) 2 Si 3 O 12 , depend on the chromium fraction x Cr  of the solid solutions as

zeitschrift für kristallographie - crystalline materials

Local mean chromium–oxygen distances in Cr 3+ -centered octahedra of natural grossular-uvarovite garnet solid solutions from electronic absorption spectra