English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Thallium(I) has a 6 s  2  non-bonding pair of valence-shell electrons, and shows a wide range of coordination environments and mean bond distances to oxygen. Conventional bond valence parameters with  B  = 0.37 Å are not suitable for modelling the soft acid – hard base Tl(I)—O interactions. Revised bond valence parameters have been derived for these bonds using structural data taken from the Inorganic Crystal Structure Database and the Cambridge Structural Database for 130 Tl(I)—O n  polyhedra. Both bond valence parameters,  R  0  and  B , were refined by minimizing the sum of the squared differences between the formal oxidation state and the experimental bond valence sums of the polyhedra. The recommended values for Tl(I)—O bonds are  R  0  = 1.927 Å,  B  = 0.50 Å, and for the assembled set of Tl—O poly hedra yield an average sum of 0.99 νu with a standard deviation of 0.12  νu . The effects of the revised Tl—O bond valence parameters upon structures containing different types of polyhedra of higher bond valence are examined with respect to the crystal structures of thallous di chromate and thallous uranyl phosphate hydrate. Crystallographic data – Tl 2 Cr 2 O 7 : triclinic,  P 1̅,  a  = 7.3150(15) Å,  b  = 7.4006(15) Å,  c  = 7.6673(16) Å,  α  = 109.941(4)°,  β  = 90.458(4)°,  γ  = 108.067(4)°,  R 1 = 5.9%; Tl 2 (UO 2 )[(UO 2 )(PO 4 )] 4 (H 2 O) 2 : monoclinic,  Cm ,  a  = 12.9798(9) Å,  b  = 15.1639(11) Å,  c  = 9.3384(6) Å,  β  = 132.310(1)°,  R 1 = 3.6%.

Revised Tl(I)–O bond valence parameters and the structures of thallous dichromate and thallous uranyl phosphate hydrate