English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Plus monthly

Global: Zendy Tools annual

Global: Zendy Tools monthly

Global: Zendy Free Plan

The crystal structure of the coordination compound [PdCl 2 (CH 4 N 6 ) 2 ],  trans -dichloridobis(1,5-diamino-1 H -tetrazole- κ N 4 )palladium(II), has been determined from X-ray powder diffraction data collected at room temperature. The structure has been solved by direct methods and refined using Rietveld analysis. The complex crystallizes in the monoclinic space group  P 2 1 / c , with Z=2. The unit cell dimensions are  a =5.73491(4),  b =11.94450(4),  c =8.61685(4)Å, and  β =99.6367(6)° with cell volume  V =581.930(5)Å 3 . A slightly distorted square-planar coordination geometry is formed around the Pd atom by two Cl atoms and two tetrazole ring N atoms of two 1,5-diamino-1H-tetrazole ligands, which are in a  trans  configuration. In the complex molecule, the planes of the tetrazole rings are inclined at 53.7(3)° with respect to the coordination plane. Intermolecular hydrogen bonds of the amino groups N—H···Cl and N—H···N ring  are responsible for formation of a three-dimensional supramolecular network. The powder pattern of the compound was strongly affected by the anisotropic line broadening. The width of the Bragg peaks was interpreted by a phenomenological microstructural approach in terms of anisotropic strain effect to complete the Rietveld refinement.

An X-ray powder study of the structure and microstructure of trans -dichloridobis(1,5-diamino-1 H -tetrazole- κ N 4 )palladium(II)