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The new compound {Mn(dien) 2 } 2 [MnSb 2 S 7 ] (dien = diethylenetriamine) was obtained under solvothermal conditions and crystallizes in the orthorhombic space group P bca . The main structural motif is the [MnSb 2 S 7 ] 4–  anion being constructed by a [MnS 4 ] 6–  tetrahedron, a [Sb III S 3 ] 3–  and a [Sb V S 4 ] 3–  anion. Each thioantimonate anion shares one edge with the Mn 2+  centered cation generating the [MnSb 2 S 7 ] 4–  unit. The two independent Mn 2+  cations in the two {Mn(dien) 2 } 2+  complexes are in a distorted octahedral environment of two tridentate acting dien molecules. One cation displays the  λδ – λλ -conformation and the other the  δλ – λδ -conformation. Several intermolecular S···H—N bonding interactions are found between the cations and the anions.

zeitschrift für kristallographie - crystalline materials

A Mixed Valent Thioantimonate(III,V): [SbS 3 ] 3–  and [SbS 4 ] 3–  as bidentate ligands: Solvothermal synthesis and crystal structure of {Mn(dien) 2 } 2 [MnSb 2 S 7 ]