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Various tin complexes containing the bidentate 2-amidoethyl ligand, H 2 NCOCH 2 CH 2 — C , O , are described. The compounds are [ 1 : (H 2 NCOCH 2 CH 2 — C , O ) 2 SnX 2 : X = Cl (two polymorphs), X = N 3  and the mixed halide, X = Cl/I] and the 1,2-dithiolates, [ 1 : X 2   = 1,2-dithiole-3-thione-4,5-dithiolate (dmt) and 1,3-dithiole-2-thione-4,5-dithiolate (dmit)]. Also discussed are the structures of co-crystalline 1 : 1 : 1 complexes, {[NBu 4 ] : [X] : ( 1) },  namely ( 2 : X = Br and I). The remaining compound considered is the hydrogen bonded 2 : 1 complex of ( 1 : X = Cl) with 18-crown-6,  3 .

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Bis(2-amidoethyl)tin compounds, (H 2 NCOCH 2 CH 2 — C , O ) 2 SnX 2 , and complexes: supramolecular arrays derived from hydrogen bonds involving the amido and X units