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SrNi 7.90(8) In 5.10(8)  was synthesized by induction melting of the elements in a sealed tantalum tube in a water-cooled silica sample chamber. The structure was refined on the basis of single crystal X-ray diffractometer data:  Cccm ,  a  = 1615.2(4),  b  = 1822.3(4),  c  = 1238.5(4) pm,  wR 2 = 0.1481, 4144 F  2  values and 150 variables). The striking structural motifs of the SrNi 7.90 In 5.10  structure are one-dimensional [Ni 7 ] cluster units (242–286 pm Ni—Ni) which are surrounded by indium atoms. The structural relationship to the other NaZn 13  superstructures is discussed on the basis of a group-subgroup scheme.

SrNi 7.90(8) In 5.10(8) – a new superstructure in the NaZn 13 family