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The structures of cocrystals of benzylidene-1,1′-bis-2-naphthol with methanol and ethanol have been studied by single crystal X-ray diffraction and  1 H-NMR spectroscopy. The cocrystal structures are stabilized by intra- and inter-molecular hydrogen bonds with the stoichiometry of a 1 : 1 host : guest. The competition experiment in the solid-liquid biphasic system between pair of guests revealed that methanol is preferentially enclathrated over ethanol in all mole fractions.

Host-guest interaction in propeller-shaped molecules. Part one: Single crystal X-ray analysis of benzylidene-1,1′-bis-2-naphthol solvent cocrystals