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Structural peculiarities of phosphate minerals are discussed in correlation with the conditions of their crystallisation or transformation in the earth crust. Close structural relations in the row: lipscombite – barbosalite – trolleite – tavorite, are analyzed in order to unterstand the nature of paragenetic associations between these minerals or their analogues (Fe-trolleite).

Phosphates with amphoteric oxo-complexes: from structural features to genetic conclusions