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The binary intermetallic phases formed by Ca, Sr, Ba, Eu and Yb with Li, Be and group 7 to 15 elements are a family of nearly 570 members, distributed over 50 compositions and 140 structure types. A graphical overview of all phases is given, and they are examined regarding their crystal chemistry, atomic sizes and volume effects in alloying.

Binary intermetallic phases formed by Ca, Sr, Ba, Eu and Yb: similarities and differences