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A computing program for calculating and visualizing the Dirichlet domains in crystal structures is described. Examples of applying the program for studying the structures of Co(III) nitropentaammines are given. The packing of complex cations, as well as the packing topology of NO 2 -fragments and their specific contacts in [Co(NH 3 ) 5 NO 2 ]Cl 2  and [Co(NH 3 ) 5 NO 2 ]Cl(NO 3 ) at ambient and high pressures are considered; the structures of different polymorphs of [Co(NH 3 ) 5 NO 2 ]I 2  are compared.

Software for calculating Dirichlet domains and examples of its application for the analysis of crystal structures of cobalt(III)nitropentaammines