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MAPO-39 is a crystalline magnesiumaluminophosphate with an idealized framework composition Al 7 MgHP 8 O 32  and a crystal structure corresponding to zeolite framework topology ATN,  FW  = 974.0, tetragonal, space group  I 4/ m ,  a  = 13.2088(2) Å,  c  = 5.2771(2) Å,  V  = 920.71(6) Å 3 ,  Z  = 1,  D x   = 1.754 Mg m −3 ,  μ  (Mo K α  ) = 0.65 mm −1 ,  λ (Mo K α  ) = 0.71069 Å,  μ (Cu K α  ) = 6.30 mm −1 ,  λ (Cu K α  ) = 1.5418 Å,  F (000) = 479. The intensities of 9733 reflections were measured on a single crystal X-ray diffractometer with Mo K α  , radiation, and 3253 reflections with Cu K α   radiation. Both data sets were combined and 1304 averaged unique intensities obtained, refinement on | F |,  R  = 0.093,  R w   = 0.024, including all unobserved and weak  F hkl  . A previously published structural model of MAPO-39 with wide 1-dimensional pores outlined by 8-rings in space group  I [unk] and based on X-ray powder diffraction data has been essentially confirmed for MAPO-39. It did not prove possible to locate precisely the template molecules in the wide pores of MAPO-39, most probably because these molecules are highly disordered. The narrower channels outlined by saddle-shaped 8-rings are small enough to be locally plugged by inverted phosphate and aluminate tetrahedra which stick out into the 1-dimensional pore. The magnesium atoms in MAPO-39 replace statistically part of the aluminium atoms in the framework. The net of primary bonds P–O and Al–O of MAPO-39 corresponds to Net 8′ predicted by Wells (Three-dimensional nets and polyhedra, New York, Wiley, 1977, p. 134) as a possible tetrahedral framework. It is the tetragonal equivalent of the hexagonal cancrinite net.

The crystal structure of the microporous solid MAPO-39 (ATN) refined from single crystal diffraction data