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The crystal structure of the title compound [C 13 H 8 Cl 2 FN] has been determined at room temperature. Colourless, needle like crystals of the compound are monoclinic, space group  P 21/ c  with unit cell dimensions  a  = 3.878(4) Å,  b  = 12.210(5) Å,  c  = 24.528(6) Å,  β  = 91.40(4)°,  Z  = 4 and  D c   = 1.534 Mgm −3  (Direct methods; full-matrix least-squares;  R  = 0.0547: 1443  hkl ). The two planar phenyl rings make a dihedral angle of 10.70(3)°. The atoms Cl(2) and F attached to one of the phenyl rings have deviations −0.008(11) Å and 0.019(11) Å, respectively. Cl(1) attached to the other phenyl ring has a deviation of −0.028(10) Å. The molecules are packed in layers parallel to (101) plane, and form C–H … F bonds.

Crystal and molecular structure of N-( p -chlorobenzylidene)-3-chloro-4-fluoroaniline