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The crystal structure of the ternary Co 2 NiAl 9  (Y 2  phase in the Co–Ni–Al system) has been solved by single crystal methods. Despite the expectation, the Y 2  structure cannot be considered as a possible approximative structure for decagonal/icosahedral phases because of the small size of the structural segments with pentagonal antiprisms and of the absence of atoms with icosahedral atomic environment. An alternative description using only transition metal polyhedrons is discussed.

The structure of the ternary phase Co 2 NiAl 9 (Y 2 )