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At room temperature, tris(1,1′-dimethyl-4,4′-bipyridinium) bishexachlorobismuthat(3-) dihydrate, [C 12 H 14 N 2 ] 3 [BiCl 6 ] 2  · 2H 2 O, crystallizes in the triclinic space group  C   i   1 ;  P [unk]; (No. 2) with  a  = 797.0(2) pm,  b  = 1215.8(2) pm,  c  = 1303.9(3) pm,  α  = 88.76(1)°,  β  = 83.01(1)°,  γ  = 73.86(1)°,  Z  = 1,  D  x  = 1.977 g/cm 3 . The cell contains three [C 12 H 14 N 2 ] 2+  cations (methyl viologen), two slightly distorted BiCl 6  octahedra ([unk] Bi–Cl  = 269.4(2) pm) and two water molecules.

The structure of [C 12 H 14 N 2 ] 3 [BiCl 6 ] 2 · 2H 2 O at room temperature