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Bis[acetatotriphenylphosphinesilver(I)] crystallizes from toluene as the hemihydrate, [CH 3 CO 2 Ag · P(C 6 H 5 ) 3 ] 2  · ½ H 2 O, which exhibits trigonal planar coordination at the silver atom. The structure has been refined to  R  = 0.051 for 3720 reflections.

Trigonal planar geometry of silver in bis[acetatotriphenylphosphinesilver(I)] hemihydrate, [CH 3 CO 2 Ag · P(C 6 H 5 ) 3 ] 2 · ½ H 2 O