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The title compound with M 2  = Mn 2  1  crystallizes in space group  C 2/ c  with  a  = 15.943(6) Å,  b  = 17.464(6) Å,  c  = 8.499(3) Å,  β  = 96.72(2)°,  V  = 2350(2) Å 3 . The homonuclear Mn–Mn bond length is 2.9332(11) Å. Title compound  2  with M 2  = MnRe crystallizes in space group  C 2/ c  with  a  = 16.058(2) Å,  b  = 17.535(4) Å,  c  = 8.593(2) Å,  β  = 96.44(1)°,  V  = 2404.3(8) Å 3 . The heteronuclear Mn–Re bond length is 3.0397(7) Å.

zeitschrift für kristallographie - crystalline materials

The homo- and heteronuclear cluster compounds ( μ -H)( μ -P(C 6 H 11 ) 2 )(CO) 8 M 2  (M 2  = Mn 2 ; Re 2 ; MnRe). A comment on the Mn – Re single bond length