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The crystal structure of  cis -[Pd{( c -C 6 H 11 ) 2 PC(S) = N(C 6 H 5 )} 2 ] has been determined at room temperature. The yellow crystals are monoclinic, space group  C 2/ c  with unit cell dimensions  a  = 19.601(2) Å,  b  = 8.2633(8) Å,  c  = 23.627(1) Å,  β  = 94.218(6)°,  Z  = 4, C 38 H 54 N 2 P 2 PdS 2  and  D  x  = 1.342 Mg m −3 . The structure was solved by direct methods and refined by a full-matrix least-squares procedure to final  R  = 0.040 using 2331 reflections. The molecule is disposed about a crystallographic two-fold axis and the ( c -C 6 H 11 ) 2 PC(S) = N(C 6 H 5 ) ligand chelates the palladium atom via the thiolato S atom and the phosphino P atom such that the two sulphur atoms are  cis  to each other; important parameters: Pd–S 2.347(1) Å, Pd–P 2.279(1) Å and S–Pd–S 100.27(7)°.

zeitschrift für kristallographie - crystalline materials

Crystal and molecular structure of  cis -bis[dicyclohexylphosphino- N -phenyl (thioformamido)]pal1adium(II):  cis [Pd{( c -C 6 H 11 ) 2 PC(S) = N(C 6 H 5 )} 2 ]