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The title compound was obtained by reduction of the corresponding lactone-bridged biaryl, by reductive cleavage with LiAlH 4 . It crystallizes from dichloromethane/petroleum ether in the monoclinic system, space group  P 2 1 / n  with  a  = 1847.0(4) pm,  b  = 793.7(2) pm,  c  = 1558.7(3) pm and  β  = 112.81(2)°.

Crystal structure of rac 1-(2-hydroxy-4,6-di- tert -butylphenyl)2-naphthalenemethanol