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The Na 4.5 FeP 2 O 8.5 F 0.5 (NFP) and Na 4 TiP 2 O 9  (NTP) crystals are superionic conductors with Na +  ion conductivity. These compounds are isostructural, but the symmetry changes taking place during the phase transition in the same temperature range (520K– 540K), are essentially different.

zeitschrift für kristallographie - crystalline materials

Structural phase transitions in the superionic conductors Na 9 {Fe 2 [PO 4 ] 4 (O, F) 2 } and Na 8 {Ti 2 [PO 4 ] 4 O 2 } in the temperature range 520–540 K