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The title compound was synthesized by photolysis of hexa- tert -butylcyclotrisilane in the presence of  N -cyclohexyl-2,3-diphenyl- α -ketoimine. It crystallizes from n-pentane monoclinically in the space group P2 1 /a with a = 1823.2(1)pm, b = 1041.1(1)pm, c = 1366.3(1) pm and β = 96.52(1)°.

Crystal structure of 2,2-di- tert -butyl-3-cyclohexyl-4,5-diphenyl-1-oxa-2-sila-3-aza-4-cyclopentene 1