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The compound (C 14 H 17 N 3 O 6 ) crystallizes in the monoclinic space group  P 2 1  with  a  = 13.640(3) Å,  b  = 4.692(1) Å,  c  = 11.299(3) Å,  β  = 93.09(1)°, ( V  = 722.1(3) Å 3 ;  Z  = 2;  D c   = 1.487 Mgm −3 ,  λ (Mo K α  ) = 0.7107 Å,  μ  = 0.11 mm −1 ,  F (000) = 340,  T  = 293 K). The structure was solved by direct methods and refined by full matrix least squares method to a final  R  = 0.039 ( R w   = 0.040). The furano ring adopts a perfect envelope E 4  conformation with the substituent C71 in equatorial and O6 in axial position. The imidazolidine ring is planar and the substituents O2,O31 and C11 are at 0.028, −0.041 and −0.200 Å from this plane. The mean planes of furano and imidazolidine rings make an angle of 108.6(1)°. The pertinent dihedral angles are 7.5(1)° (phenyl-imidazoline); 115.9(1)° (phenyl-furane), and 7.1(3)° (imidazoline-amide). The molecules are stakked along the  b  axis forming two infinite chains through an intermolecular H-bond O71 … O6.

Structure of 1-carbamoyl-3-phenyl-(1,2-dideoxy- α -D-glucofurano) [1,2-d]imidazolidin-2-one