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N,N′-ethylene-bis-(tetronic-acid-3-formiminato)-copper(II)/K1 crystallizes in space group  P 2 1 / n : C 12 H 10 CuN 2 O 6  × H 2 O;  a  = 8.439(5) Å;  b  = 12.762(1) Å;  c  = 12.582(1) Å;  β  = 99.02(3)°;  V  = 1338.3 Å 3 ;  Z  = 4;  D x   = 1.783 gcm −3 ; Mo K α   = 0.71069 Å;  μ  = 16.71 cm −1 ;  F (000) = 732;  T  = 293 K; Conventional  R  = 0.037;  R w   = 0.040 for 1633 observed reflections.

Crystal structures of nickel(II) and copper(Il)-Schiff-bases complexes with tetramic and tetronic acid subunits