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The title compound was prepared from the corresponding alcohol, by hydroxy/halogen exchange reaction. It crystallizes from petroleum ether in the orthorhombic system, space group  Pbcn , with  a  = 2830.1(6) pm,  b  = 821.7(2) pm,  c  = 1444.2(4) pm.

Crystal structure of 2-bromomethyl-1-(2′-methoxy-3,5-dimethyl)-naphthalene 1