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The crystal structure of Sr 3 (VO 4 ) 2  has been refined using X-ray single-crystal diffractometry. Sr 3 (VO 4 ) 2  crystallizes in the space group  R [unk] m  (No. 166) with cell dimensions (hexagonal system):  a  = 5.619(1) Å,  c  = 20.100(4) Å,  Z  = 3. The crystal structure consists of a three-dimensional arrangement of VO 4  tetrahedra, SrO 12  icosahedra and SrO 10  {1,6,3} polyhedra. The compound Sr 3 (VO 4 ) 2  is isostructural with Sr 3 (PO 4 ) 2  and palmierite PbK 2 (SO 4 ) 2 .

Crystal structure refinement of strontium tetraoxo-vanadate(V), Sr 3 (VO 4 ) 2