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Cp  o  2 ZrCl 2  ( Cp  o  =  η  5 -C 5 Me 4 Et) crystallizes in the monoclinic space group  P 2 1 / n  (No. 14) ( T  = 298 K) with  a  = 8.477(4),  b  = 18.280(7),  c  = 14.372(7) Å,  β  = 92.88(7)°,  V  = 2224.3 Å 3  and  Z  = 4. The refinement gives final  R  values  R  = 0.039 and  R  w  = 0.039 for 3860 observed symmetry-independent reflections. The Zr atom is tetrahedrally coordinated by two  Cp  o  ligands and two chloro ligands. The  Cp  o  ligands adopt a staggered conformation.

Struktur von bis(tetramethylethylcyclopentadienyl)zirkondichlorid, Cp 2 o ZrCl 2 ( Cp o = η 5 -C 5 Me 4 Et)