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The title compound, C 43 H 79 O 2 NPt, crystallizes in the monoclinic system, space group  P 2 1 / c , with  a  = 20.444(8) Å,  b  = 12.220(4) Å,  c  = 18.303(7) Å,  β  = 101.6(4),  Z  = 4. The coordination of Pt is slightly distorted square-planar, the backbone of the  hydro -aldoamidic ligand is almost planar; its mean plane is orthogonal to the coordination plane of Pt. The crystal structure has been refined to  R  = 0.054 for 3518 observed reflections.

The crystal structure of Pt(II)- trans -[(bis-tricyclohexylphosphine)( η 1 - hydro -formyl- ter -butylamido)(hydride)]