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About 250 inorganic structure types, reported with a monoclinic centred unit cell, were tested for overlooked trigonal symmetry and the metrics of the different “best” monoclinic cells describing an  hR  Bravais lattice were studied. Three-fold axes were detected in the compounds listed below, for which the crystallographic data were converted to the corresponding trigonal space groups:

zeitschrift für kristallographie - crystalline materials

Overlooked trigonal symmetry in structures reported with monoclinic centred Bravais lattices; trigonal description of Li 8 Pb 3 , PtTe, Pt 3 Te 4 , Pt 2 Te 3 , LiFe 6 Ge 4 , LiFe 6 Ge 5 , CaGa 6 Te 10  and La 3.266 Mn 1.1 S 6