English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The crystal structure of an orthorhombic form of 1,2-bis-(phenylsulfonyl)ethane, C 14 H 14 O 4 S 2 , was studied by X-ray diffraction at 86 K. The space group is  Pna 2 1 ,  a  = 24.249(1) Å,  b  = 11.079(1) Å,  c  = 5.257(1) Å, and  Z  = 4. Two equivalent sets of intensities were collected to a maximum (sin θ )/ λ  = 0.904 A −1  with Mo Kα  radiation. The data were corrected for absorption, scan truncation, extinction and multiple diffraction in addition to the routinely applied corrections before the final averaging. The structure was solved by Patterson methods, and leastsquares refinements were carried out within different shells of reciprocal space. With all data, 3856  F  0 ,  R  is 0.027. The parameters obtained with (sin θ )/ λ  &gt; 0.60 Å −1  give the best description of the structure ( R  = 0.030, 2481  F  0 ), and a correction for rigid-body motion was applied to the two S-phenyl fragments. Relative to the values from the refinement with all data, the uncorrected aromatic C—C distances are longer by an average of 0.0042 Å. All S—C bonds are in good agreement with the mean values for aromatic sulfones. One phenyl ring is in an anisotropic environment which causes rather large variations in the atomic displacement parameters and differences between pairs of bonds over the 1,4-diagonal. The other ring has almost exact  C  2v  symmetry. The sequence C—C—S—C(phenyl) is oriented  trans , compared to the  gauche  arrangement in the monoclinic form. The molecular packing is very different in the monoclinic and the orthorhombic forms.

Crystal structure of an orthorhombic form of l,2-bis(phenylsulfonyl)ethane at 86 K