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CsBaCr 3 F 12  is monoclinic (S.G.:  C 2/ c ):  a  = 17.184(4) Å,  b  = 9.886(2) Å,  c  = 15.037(5) Å,  β  = 124.32(2)°,  Z  = 8. The structure was solved from single crystal data using 2218 independent reflections ( R  = 0.053,  R w   = 0.042). The structure is built up from [Cr 3 F 12 ] layers of vertex-sharing octahedra separated by cesium and barium ions located in an ordered way. The topology of the layers is unique and illustrates a case of plane net predicted by O'Keeffe, yet unknown in nature but imaginated by arabic artists in the 18th century.

Crystal chemistry, plane nets and arabic mosaics: the structure of CsBaCr 3 F 12 , a new MX 4 network