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The crystal and molecular structure of 1H[1]benzothieno[2,3d]imidazole ( 1 ) has been determined from three dimensional X-ray data. C 9 H 6 N 2 S is orthorhombic, space group  P 2 1 2 1 2 1 , with  Z  = 12 in a cell of dimensions  a  = 29.275(3) Å,  b  = 13.635(3) Å,  c  = 6.166(2) Å. The asymmetric unit is made of three independent molecules linked by three hydrogen bonds.

Crystal structure and tautomerism of 1H[1]benzothieno[2,3d]imidazole