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The crystal structure of Cs 0.35 Al 0.35 Si 2.65 O 6  has been determined with direct methods from X-ray four-circle single-crystal diffractometer data at 293 K. The space group is monoclinic,  B 2 1  with  Z  = 4;  a  = 7.3585(4) Å;  b  = 5.0334(3) Å;  c  = 15.950(1) Å;  β  = 90.778(9) 0 ;  V  = 590.7 Å 3 ;  D  c  = 2.55g cm −3 ,  D  m  = 2.56g cm −3 . The refinement converged to  R  = 0.044. The aluminosilicate framework is isotypical with the framework of bikitaite. The Cs atom is located in the large channel coordinated by ten oxygens in the range 3.24 Å to 3.58 Å.

The crystal structure of Cs 0.35 Al 0.35 Si 2.65 O 6 , a cesium-aluminosilicate with the bikitaite framework