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The title compound CuCl(C 2 N 2 S 2 H 4 ) crystallizes in the orthorhombic system, space group Pbca with parameters  a  = 15.576(3),  b  = 6.923(3),  c  = 11.416(3) Å. The crystal structure reveals infinite ribbons … Cu[SC(NH 2 )C(NH 2 )S]Cu … running along the  a  axis; these ribbons are coupled by two interribbon interactions between copper and sulfur atoms; this weak bonding gives a distance Cu – S = 2.68(2) Å. Within the ribbon the copper I is bonded to two sulfur atoms pertaining to two different rubeanates and a chlorine atom: Cu – S = 2.24(1) and 2.25(1) Å and Cu – Cl = 2.31(1) Å. The coordination of copper(I) is described as being [3 + 1] the weak interribbon bonding pulling the copper out of the trigonal coordination plane by some 0.38 Å.

Complexes métalliques de l'acide rubéanique. II. Etude structurale, par diffraction des rayons X, du rubéanate de cuivre(I): CuCl(C 2 N 2 S 2 H 4 )