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The mineral Srilankit (Zr 0,33 Ti 0,67 )O 2  crystallizes orthorhombic in the space group  Pbcn  with the lattice constants  a  = 4,706(5),  b  = 5.553(5),  c  = 5.024(4) Å,  Z  = 4. The crystal structure was determined from single crystal X-ray diffractometer data and refined to  R  = 3.4%. Zr and Ti are distributed at random among the sites of the  α -PbO 2  structure. Each metal ion is bonded to six oxygens forming distorted (Ti,Zr)O 6 -octahedra with metal-oxygen distances of 1.924(4), 2.002(4) and 2.138(4) Å.

(Zr 0,33 Ti 0,67 )O 2 – ein natürliches Zirkonium-Titanoxid mit α -PbO 2 -Struktur