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The title compound crystallizes in the space group  P 2 1 / b  with two molecules in the asymmetric unit. The structure was solved by  MULTAN  and Fourier methods ( R  = 0.043). The Cl—C distances at the trioxolane ring are shortened, the other Cl—C distances enlarged. The C—C distances vary from 1.490 to 1.553 Å. The other bond lengths are normal. The deviations from the C( sp  2 ) bond angles are explained by Cl—Cl repulsion. The C( sp  3 ) angles vary from 100.0 to 114.9°. Endocyclic torsion angles and deviations from the best planes of three atom groups are listed.

Die Kristall- und Molekülstruktur von 1,3,7,8,8a,9-Hexachlor-4a,5,6,8a-tetrahydro-1,3epidioxy-4,6-methanoisochroman