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The complexation of redox sensitive elements by humic acid (HA), described through the charge neutralisation model (CNM), has been reviewed in order to have a comprehensive scope. The data acquired in HUMICS program on thorium(IV), and data available in the literature, were reinterpreted according to the CNM, and adapted to uranium(IV), neptunium(IV) and plutonium(IV) through analogy in order to draw a boundary prediction. Otherwise, available data obtained in the framework of the CNM were used, or adapted if necessary, for other redox states when the analogy is justified,   i.e.   Am 3+ -Cm 3+  for Pu 3+ , NpO 2  +  for PuO 2  +  and UO 2  2+  for PuO 2  2+ .

Prognosticating the humic complexation for redox sensitive actinides through analogy, using the charge neutralisation model