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The reliability and accuracy of actinide measurement in environmental samples strongly depend on the  α -spectrum deconvolution process used to identify all radionuclides present in the sample, and the necessity to take into account internal conversion is demonstrated. In this process, all actinides can be resolved as the sum of three peaks: the main alpha transition and two sum peaks for which the additional  α  ray is merged with the internal conversion on  L -shell peak and with all other conversions on  M -shell,  N -shell,  etc.

Deconvolution of alpha liquid scintillation spectra for quantitative analysis of actinide elements in water samples