English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

For the first time, the interaction of uranium(VI) with citric acid and oxalic acid in aqueous solution was investigated using time-resolved laser-induced fluorescence spectroscopy (TRLFS) between pH 2 and 4. The complex species UO 2 cit −  and (UO 2 ) 2 (cit) 2  2−  formed in citrate medium as well as UO 2 ox and UO 2 (ox) 2  2−  formed in oxalate medium show no luminescence emissions at room temperature. However, by coupling the fluorescence measurement technique with a low temperature system (−120 ºC, cryo-TRLFS), emission signals of the various complex species could be detected. The emission signals are bathochromic shifted in comparison to the emission maxima of the uncomplexed uranium(VI) cation. Using the spectroscopic data, the corresponding complex formation constants were calculated, which corroborate literature data.

radiochimica acta

Luminescence properties of uranium(VI) citrate and uranium(VI) oxalate species and their application in the determination of complex formation constants