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The solvation of the Eu-perchlorate (ClO 4  – ) and triflate (CF 3 SO 3  – , OTf – ) salts as well as of Cm(ClO 4 ) 3  and Am(ClO 4 ) 3  in the ionic liquid C 4 mimTf 2 N (1-butyl-3-methylimidazolium-bis(trifluoromethylsulfonyl)imide) has been comparatively investigated by application of laser fluorescence spectroscopy and X-ray absorption spectroscopy. Moreover, the ClO 4  – /OTf –  ligand exchange reaction for the two actinide cations has been analyzed by the same spectroscopic techniques. A structural model for the different complexes was determined by the interpretation of the spectroscopic data. The lanthanide and the two actinide cations show the same coordination in C 4 mimTf 2 N. Moreover, a sequence for the strength of complexing ligands could be deduced from the spectroscopic data for the lanthanide and the two actinides: ClO 4  – &gt;OTf – ≥Tf 2 N – &gt;H 2 O.

TRLFS and EXAFS investigations of lanthanide and actinide complexation by triflate and perchlorate in an ionic liquid