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Three new uranium(VI) compounds have been prepared with glycine (Hgly),  N -(2-mercaptopropionyl)glycine (Hmpg) and 2,2′-dithiobis( N -propionylglycine) (tpg). The crystal structure of [UO 2 (Hgly) 2 Cl 2 ] has been solved, revealing the uranium atom to be seven-co-ordinated. The two zwitterionic glycines are coordinated to uranium atom by the carboxylate groups, one in a monodentate and the other in a bidentate mode. Solid state studies and low temperature  1 H,  13 C, 2D COSY and HMQC solution NMR spectra of the [UO 2 (mpg)(CH 3 COO)], show that mpg coordinates uranium atom by the carboxylate group.

radiochimica acta

Investigation on uranyl interaction with bioactive ligands. Synthesis and structural studies of the uranyl complexes with glycine and  N -(2-mercaptopropionyl)glycine