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Radiolysis of water is a phenomenon which alters the prevailing conditions in the nearfield of a final geological repository for high-level nuclear waste (HLW), because the nominally anoxic conditions in the repository may change due to the production of oxidants close to the solid-liquid interface of the fuel, caused by the alpha radiolysis of water.

Contrary effects of the water radiolysis product H 2 O 2 upon th dissolution of nuclear fuel in natural ground water and deionized water