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A marked 'oxygen effect' is observed for several cobalt complexes in thermal annealing. Kinetic data are reported for recoil damage, after  59 Co ( γ ,  n )   58 Co and  59 Co ( n,  γ)   60 Co- reactions in trisacetylacetone Co (III) and bis-salicylaldehyde triethylenetetramine Co (III) chloride respectively. When the thermal treatment is carried out in N 2  or vacuum (viz., in absence of oxygen), the magnitude of Saturation anneal is considerably higher. Aliquots annealed to Saturation in presence of air can be made to undergo further annealing, if the thermal treatment is continued at the same temperature but in the absence of air (in vacuum or nitrogen).

radiochimica acta

Oxygen-Effect in Annealing of Recoil Damage in Cobalt Chelates-Tris-Acetyl-Acetone Co(III) and Bis-Salicylaldehyde Triethylenetetramine Co(III) Chloride