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C 24 H 16 Cl 2 Cu 2 N 4 , monoclinic,  C 12/ c 1 (no. 15),  a  = 19.709(3) Å,  b  = 14.830(3) Å,  c  = 15.208(3) Å, β = 103.096(2)°,  V  = 4329.5 Å 3 ,  Z  = 8,  R  gt  (F)  = 0.027,  wR  ref  (F  2  )  = 0.089,  T  = 273 K.

Crystal structure of bis(1,10-phenanthroline)copper(I) dichlorocuprate(I), [Cu(C 12 H 8 N 2 ) 2 ][CuCl 2 ]