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C 18 H 42 Br 9 ClN 6 O 6 Si, trigonal,  R 3 (no. 148),  a  = 18.496(3) Å,  c  = 9.939(2) Å,  V  = 2944.7 Å 3 ,  Z  = 3,  R  gt  (F)  = 0.056,  wR  ref  (F  2  )  = 0.176,  T  = 180 K.

Crystal structure of hexakis(N,N-dimethylformamide-O)silicon(IV) tris(tribromide) chloride, [Si{(CH 3 ) 2 NCHO} 6 ][Br 3 ] 3 Cl