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Br 6 Gd 4 Si, orthorhombic,  P bam  (no. 55),  a  = 13.172(2) Å,  b  = 13.982(1) Å,  c  = 4.083(1) Å,  V  = 752.0 Å 3 ,  Z  = 2,  R  gt  (F)  = 0.026,  wR  ref  (F  2  )  = 0.061,  T  = 293 K.

Crystal structure of tetragadolinium monosilicide hexabromide, Gd 4 SiBr 6