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C 12 H 36 Li 4 N 8 Si 2 , monoclinic,  C 12/ c 1 (No. 15),  a  = 19.468(4) Å,  b  = 12.870(3) Å,  c  = 20.568(4) Å, β = 117.88(3)°,  V  = 4555.3Å 3 ,  Z  = 8,  R  gt  (F)  = 0.052,  wR ref (F  2  )  = 0.148,  T  = 293 K.

Crystal structure of di(N-lithiummethylamino)bis(dimethylamino)silane, Si(NLiCH 3 ) 2 (N(CH 3 ) 2 ) 2