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Platinum-styrene complexes are prepared by reacting a platinum halide with styrene or substituted styrenes in the presence of a basic material for a sufficient amount of time to form a complex having more than one and less than four gram atoms of halogen per gram atom of platinum. These platinum-styrene complexes may be used to promote the addition of organosilicon compounds having at least one 3BOND SiH group per molecule to a compound containing aliphatic unsaturation.

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