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Three experimental polyoxyethylene sorbitan monolaurate derivatives were synthesized with molecular fingerprinting techniques applied to experimental materials, confirming the target compounds had been produced. Chemical property measurements were compiled that aligned with theoretical predictions and physical property measurements confirmed their intentional differences yielded the anticipated changes in surfactant behavior. Imidacloprid uptake data confirmed penetration of leaf cuticles was enhanced in the presence of polyoxyethylene sorbitan monolaurates with several experimental materials providing uptake equivalent to reference material. Select materials were included in field and greenhouse trials where observations included good biological response with a range of individual herbicides as well as improved control of volunteer glyphosate tolerant corn with mixtures of glyphosate and clethodim over the control nonionic surfactant adjuvant when applied as a tank-added adjuvant. Antagonism of annual grass control was not observed. Manuscript received December 15, 2013; accepted for publication December 16, 2014; published online February 24, 2015. Croda Inc., New Castle, DE 19720. Southern Illinois Univ., Carbondale, IL 62901. Univ. of Nebraska at Lincoln, North Platte, NE 68588. ASTM 34th Symposium on Pesticide Formulation and Delivery Systems: Translating Basic Science into Products on Oct. 22–24, 2013 in Jacksonville, FL. Copyright VC 2015 by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. PESTICIDE FORMULATION AND DELIVERY SYSTEMS: 34TH VOLUME, TRANSLATING BASIC SCIENCE INTO PRODUCTS 76 STP 1579, 2015 / available online at www.astm.org / doi: 10.1520/STP157920130188

Physical and Biological Effects of Modified Polysorbate 20