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Instead of water reversed micelles can also be formed with polar organic solvents possessed with high dielectric constant and very low solubility in oil phase. Nonaqueous reverse micelles or microemulsions represent an interesting microreactors for various reactions, especially for reactions, where reagents can react with water. Study of localization places of molecular probes in organic polar pockets of reverse micelles is topical. The solvatochromic behavior of optical probes ortho-nitroaniline (o-NA) and methyl orange (MO) was studied in nonaqueous reverse micelles on the basis of surfactants sodium bis (2-ethylhexyl) sulfosuccinate (AOT) and polyoxyethylene (4) lauryl ether (C 12 E 4 ) and polar organic solvents (acetonitrile, dimethylformamide, glacial acetic acid, etc.) insoluble in oil phase hexane. The strength of binding of o-NA and MO to AOT and C 12 E 4  reversed micelles was assesssed via binding constant ( K    b   ) and association degree ( α ) respectively. Donor, acceptor, or dipole-dipole interactions ability of the solvent to the head groups of surfactant was taken into account in order to explain results obtained with UV–visible spectroscopic method. The binding constants of o-NA with reverse AOT micelles in the presence of various solvents in the pockets of reversed micelles increase in the following row water &lt; glacial acetic acid &lt; acetonitrile &lt; dimethylformamide &lt; dimethyl sulfoxide, but this sequence is reversed when o-NA binds to C 12 E 4  reverse micelles. The high value of the proton donor or acidity parameter in the water molecule ( x    d    = 0.37) determines the weak binding of o-NA to the head AOT groups ( K    b    = 20.8) in case of aqueous reverse micelles. The high value of the dipole parameter in the dimethylformamide molecule ( x    n    = 0.40) promotes its strong interaction with nonionic polyoxyethylene groups of C 12 E 4 , which results in low value of binding constant ( K    b    = 26.5) in case of optical probe o-NA and low value of association degree ( α  = 0.60) using MO as absorption probe. The results of this article will contribute to the improvement of the concept of interfacial processes, viz.: (i) some issues of supramolecular chemistry, (ii) revealing the contribution of parameters of donor, acceptor or dipole-dipole interaction in a polar organic solvent at the surfactant/nonpolar organic solvent interface, and (iii) features of the dissolution of optical probes in non-aqueous reverse micelles.

zeitschrift für physikalische chemie

Study of structure of nonaqueous reverse micelles with o-nitroaniline and methyl orange as molecular probes: comparison with an aqueous reverse micelles